Yusubov, Mekhman S., Soldatova, Natalia S., Postnikov, Pavel S., Valiev, Rashid R., Yoshimura, Akira, Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667, Nemykin, Victor N. and Zhdankin, Viktor V.
2019.
2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(v) oxidant.
Chemical Communications
55
, pp. 7760-7763.
10.1039/C9CC04203B
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Official URL: http://dx.doi.org/10.1039/C9CC04203B
Abstract
A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.
| Item Type: | Article |
|---|---|
| Date Type: | Publication |
| Status: | Published |
| Schools: | Schools > Chemistry |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| Date of First Compliant Deposit: | 19 June 2019 |
| Date of Acceptance: | 7 June 2019 |
| Last Modified: | 15 Nov 2024 20:30 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/123567 |
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