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2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(v) oxidant

Yusubov, Mekhman S., Soldatova, Natalia S., Postnikov, Pavel S., Valiev, Rashid R., Yoshimura, Akira, Wirth, Thomas, Nemykin, Victor N. and Zhdankin, Viktor V. 2019. 2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(v) oxidant. Chemical Communications 55 , pp. 7760-7763. 10.1039/C9CC04203B

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A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Date of First Compliant Deposit: 19 June 2019
Date of Acceptance: 7 June 2019
Last Modified: 19 Jan 2021 04:19

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