Synthesis, characterisation, and reactivity of novel pseudocyclic hypervalent iodine reagents with heteroaryl carbonyl substituents

Qurban, Jihan, Elsherbini, Mohamed, Alharbi, Haifa and Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 2019. Synthesis, characterisation, and reactivity of novel pseudocyclic hypervalent iodine reagents with heteroaryl carbonyl substituents. Chemical Communications 55 , pp. 7998-8000. 10.1039/C9CC03905H

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Abstract

Two new hypervalent iodine reagents containing furan and thiophene moieties in addition to a carbonyl group in the vicinity of the iodine atom were synthesised and characterised. The X-ray analysis of both compounds revealed a strong intramolecular contact between the carbonyl oxygen and the hypervalent iodine atom with tosylate as a counter ion. The two reagents showed a broad range of synthetic applications and proved to be versatile oxidizing agents.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Date of First Compliant Deposit:	19 June 2019
Date of Acceptance:	17 June 2019
Last Modified:	16 Nov 2024 12:00
URI:	https://orca.cardiff.ac.uk/id/eprint/123569

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