Novel approach to the high-yield synthesis of tertiary alcohols using organoboranes

Hughes, Rosemary J., Pelter, Andrew and Smith, Keith 1974. Novel approach to the high-yield synthesis of tertiary alcohols using organoboranes. Journal of the Chemical Society. Chemical communications (21) , 863a. 10.1039/C3974000863A

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Abstract

Trialkylmethanols (R12R2COH) are produced in essentially quantitative yields by treatment of trialkylboranes successively in the same vessel with 1-lithio-1,1-bis(phenylthio)alkene (–30 to 20°), HgCl2(–78 to 0°) and alkaline hydrogen peroxide (20°).

Item Type:	Article
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	0022-4936
Last Modified:	04 Jun 2017 02:50
URI:	https://orca.cardiff.ac.uk/id/eprint/12578

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