The chemistry of organoborates. Part 3. Protonation of trialkylcyanoborates

Pelter, Andrew, Hutchings, Michael G. and Smith, Keith ORCID: https://orcid.org/0000-0003-4838-5651 1975. The chemistry of organoborates. Part 3. Protonation of trialkylcyanoborates. Journal of the Chemical Society, Perkin Transactions 1 (2) , pp. 142-145. 10.1039/P19750000142

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Abstract

Protonation of trialkylcyanoborates in bis-(2-methoxyethyl) ether (diglyme) leads to migration of two alkyl groups from boron to carbon and the production of derivatives of 1,4-diaza-2,5-diboracyclohexane. On oxidation, these compounds yield ketones.

Item Type:	Article
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	RSC Publishing
ISSN:	0300-922X
Last Modified:	04 Jun 2017 02:50
URI:	https://orca.cardiff.ac.uk/id/eprint/12581

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