Improved synthesis of tertiary alcohols from reactions of organoboranes with 2-lithio-1,3-benzodithioles

Ncube, S., Pelter, A. and Smith, Keith 1979. Improved synthesis of tertiary alcohols from reactions of organoboranes with 2-lithio-1,3-benzodithioles. Tetrahedron Letters 20 (21) , pp. 1895-1896. 10.1016/S0040-4039(01)86872-6

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Abstract

Treatment of trialkylboranes with 2-lithio-1,3-benzodithioles and then mercuric chloride (or methyl fluorosulhonate) followed by oxidation gives tertiary alcohols in high yields. The method is applicable to reactions of hindered organoboranes that fail using 1-lithio-1,1-bis(phenylthio)alkanes.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Elsevier
ISSN:	0040-4039
Last Modified:	04 Jun 2017 02:50
URI:	https://orca.cardiff.ac.uk/id/eprint/12635

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