Reactions of organoboranes and 2-lithio-2-alkyl-1,3-benzodithioles: A new, improved synthesis of ketones

Ncube, S., Pelter, A. and Smith, Keith 1979. Reactions of organoboranes and 2-lithio-2-alkyl-1,3-benzodithioles: A new, improved synthesis of ketones. Tetrahedron Letters 20 (21) , pp. 1893-1894. 10.1016/S0040-4039(01)86871-4

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Abstract

Reactions of trialkylboranes with 2-lithio-2-alkyl-1,3-benzodithioles followed by oxidation give ketones in good yields. This method is far less subject to steric hindrance than the analogous reactions using anions derived from bis(phenylthio)alkanes.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Elsevier
ISSN:	0040-4039
Last Modified:	04 Jun 2017 02:50
URI:	https://orca.cardiff.ac.uk/id/eprint/12636

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