A sound sequence to triphenylphosphino dibromoplatinum(II) complexes – solvothermal preparation of trans-[PtBr(µ‐Br)(PPh3)]2

Fioco, David ORCID: https://orcid.org/0000-0003-3714-2742, Belli Dell'Amico, Daniela, Labella, Luca, Marchetti, Fabio and Samaritani, Simona 2019. A sound sequence to triphenylphosphino dibromoplatinum(II) complexes – solvothermal preparation of trans-[PtBr(µ‐Br)(PPh3)]2. European Journal of Inorganic Chemistry 2019 (36) , pp. 3970-3974. 10.1002/ejic.201900711

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Abstract

A sound synthetic procedure for the preparation of trans‐[PtBr(µ‐Br)(PPh3)]2 is described. The species was fully characterized and used to obtain [PtBr2(PPh3)(L)] complexes (L = DMSO, p‐toluidine, pyridine) by a bridge‐splitting reaction. All products were fully characterized by NMR spectroscopy, together with cis‐[PtBr2(PPh3)(NCCH3)], obtained as an intermediate in the synthesis of the dinuclear precursor. Cis‐[PtBr2(PPh3)(NCCH3)] was also studied by X‐ray diffraction.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Publisher:	Wiley
ISSN:	1434-1948
Date of First Compliant Deposit:	4 November 2019
Date of Acceptance:	28 August 2019
Last Modified:	15 Nov 2024 17:45
URI:	https://orca.cardiff.ac.uk/id/eprint/126412

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