Fioco, David ![]() |
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Official URL: https://doi.org/10.1002/ejic.201900711
Abstract
A sound synthetic procedure for the preparation of trans‐[PtBr(µ‐Br)(PPh3)]2 is described. The species was fully characterized and used to obtain [PtBr2(PPh3)(L)] complexes (L = DMSO, p‐toluidine, pyridine) by a bridge‐splitting reaction. All products were fully characterized by NMR spectroscopy, together with cis‐[PtBr2(PPh3)(NCCH3)], obtained as an intermediate in the synthesis of the dinuclear precursor. Cis‐[PtBr2(PPh3)(NCCH3)] was also studied by X‐ray diffraction.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Publisher: | Wiley |
ISSN: | 1434-1948 |
Date of First Compliant Deposit: | 4 November 2019 |
Date of Acceptance: | 28 August 2019 |
Last Modified: | 15 Nov 2024 17:45 |
URI: | https://orca.cardiff.ac.uk/id/eprint/126412 |
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