Para-selective mononitration of alkylbenzenes under mild conditions by use of benzoyl nitrate in the presence of a zeolite catalyst

Smith, Keith, Fry, K., Butters, M. and Nay, B. 1989. Para-selective mononitration of alkylbenzenes under mild conditions by use of benzoyl nitrate in the presence of a zeolite catalyst. Tetrahedron Letters 30 (39) , pp. 5333-5336. 10.1016/S0040-4039(01)93779-7

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Abstract

Toluene and other alkylbenzenes are mononitrated in essentially quantitative yield at ambient temperature by benzoyl nitrate in the presence of aluminium/proton exchanged large port mordenite; the reaction is highly para-selective. The use of benzoyl nitrate in combination with an acidic zeolite catalyst provides a convenient method for high yielding and para-selective nitration of alkylbenzenes.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Elsevier
ISSN:	0040-4039
Last Modified:	04 Jun 2017 02:50
URI:	https://orca.cardiff.ac.uk/id/eprint/12645

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