Hindered organoboron groups in organic synthesis. 14. stereoselective synthesis of alkenes by the boron-wittig reaction using aliphatic aldehydes

Pelter, A., Smith, Keith, Elgendy, S. and Rowlands, M. 1989. Hindered organoboron groups in organic synthesis. 14. stereoselective synthesis of alkenes by the boron-wittig reaction using aliphatic aldehydes. Tetrahedron Letters 30 (41) , pp. 5647-5650. 10.1016/S0040-4039(01)93821-3

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Abstract

In the presence of HX, carbanions Mes2BCHLiR1 react with aliphatic aldehydes to give alkenes. The stereochemistry of the product alkene depends upon the nature of HX.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Elsevier
ISSN:	0040-4039
Last Modified:	04 Jun 2017 02:50
URI:	https://orca.cardiff.ac.uk/id/eprint/12646

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