Hindered organoboron groups in organic synthesis. 17 [1]. Synthesis of 2,4,6-triisopropylphenylborane (TripBH2)2, a useful alternative to thexylborane

Pelter, Andrew, Smith, Keith, Buss, Dieter and Jin, Zhao 1992. Hindered organoboron groups in organic synthesis. 17 [1]. Synthesis of 2,4,6-triisopropylphenylborane (TripBH2)2, a useful alternative to thexylborane. Heteroatom Chemistry 3 (3) , pp. 275-277. 10.1002/hc.520030313

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Abstract

2,4,6-Triisopropylphenylborane (tripylborane, TripBH2) resembles thexylborane in having a single, bulky organic group attached to boron, but the group is aromatic rather than aliphatic. The compound has been synthesized by two alternative routes, one involving direct reduction of dimethoxytripylborane and the other involving redistribution between ditripylborane and borane. It is a solid which is considerably more stable than thexylborane.

Item Type:	Article
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Wiley-Blackwell
ISSN:	1042-7163
Last Modified:	04 Jun 2017 02:51
URI:	https://orca.cardiff.ac.uk/id/eprint/12669

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