Highly efficient one-step conversion of cyclohexane to adipic acid using single-site heterogeneous catalysts

Raja, Robert, Thomas, John Meurig, Xu, Mingcan, Harris, Kenneth David Maclean ORCID: https://orcid.org/0000-0001-7855-8598, Greenhill-Hooper, Michael and Quill, Kieran 2006. Highly efficient one-step conversion of cyclohexane to adipic acid using single-site heterogeneous catalysts. Chemical Communications- Royal Society of Chemistry (4) , pp. 448-450. 10.1039/B513583D

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Abstract

A solid source of ‘active’ oxygen (acetylperoxyborate, APB), when dissolved in aqueous solution in the presence of a single-site microporous catalyst containing redox centres (FeIIIAlPO-31, MnIIIAlPO-5, FeIIIAlPO-5), converts cyclohexane with high efficiency (ca. 88%) and exceptionally high selectivity (ca. 81%) to adipic acid at 383 K; this procedure is also effective in converting styrene to styrene oxide and α-pinene and (+)-limonene to their corresponding epoxides.

Item Type:	Article
Status:	Published
Schools:	Schools > Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Last Modified:	18 Oct 2022 13:10
URI:	https://orca.cardiff.ac.uk/id/eprint/12768

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