Expanded-ring and backbone-functionalised N-heterocyclic carbenes

Iglesias, Manuel Alonso, Beetstra, Dirk Johannes, Cavell, Kingsley John, Dervisi, Athanasia ORCID: https://orcid.org/0000-0002-0590-5496, Fallis, Ian Andrew ORCID: https://orcid.org/0000-0001-7361-0182, Kariuki, Benson ORCID: https://orcid.org/0000-0002-8658-3897, Harrington, Ross W., Clegg, William, Horton, Peter N., Coles, Simon J. and Hursthouse, Michael B. 2010. Expanded-ring and backbone-functionalised N-heterocyclic carbenes. European Journal of Inorganic Chemistry 2010 (11) , pp. 1604-1607. 10.1002/ejic.200901182

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Abstract

An unsaturated seven-membered amidinium salt 7 decomposes in the presence of metal salts under basic conditions. However, 7 readily forms a Diels–Alder cycloadduct with CpH from which the RhI complexes may be prepared. Thus, structurally elaborate, sterically crowded carbene ligand complexes bearing peripheral unsaturated functionality are available in a short versatile synthesis.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry Cardiff Catalysis Institute (CCI)
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	Carbene ligands; Cycloaddition; Rhodium; Ligand design; Isomers
Publisher:	Wiley
ISSN:	1434-1948
Last Modified:	18 Oct 2022 13:11
URI:	https://orca.cardiff.ac.uk/id/eprint/12849

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