Rhodium complexes of cyclopropenylidene carbene ligands: Synthesis, structure, and hydroformylation catalysis

Green, Michael, McMullin, Claire L., Morton, George J. P., Orpen, A. Guy, Wass, Duncan F. ORCID: https://orcid.org/0000-0002-0356-7067 and Wingad, Richard L. 2009. Rhodium complexes of cyclopropenylidene carbene ligands: Synthesis, structure, and hydroformylation catalysis. Organometallics 28 (5) , pp. 1476-1479. 10.1021/om801031a

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Abstract

Rhodium(III) cyclopropenylidene complexes of the type [RhCl3(PPh3)2(2,3-di(aryl)cyclopropenylidene)] (Aryl = C6H5, 4-C6H4F) are synthesized via oxidative addition of 1,1-dichloro-2,3-diarylcyclopropene fragments to rhodium(I) precursors. The molecular structure of these complexes has been determined. Attempted hydroformylation of 1-hexene with these complexes leads to catalysis results which are strongly suggestive of decomposition of the carbene complex.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry Cardiff Catalysis Institute (CCI)
Publisher:	American Chemical Society
ISSN:	0276-7333
Last Modified:	07 Nov 2022 09:20
URI:	https://orca.cardiff.ac.uk/id/eprint/128772

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