A neutral, monomeric germanium(I) radical

Woodul, William D., Carter, Emma ORCID: https://orcid.org/0000-0001-6691-2377, Müller, Robert, Richards, Anne F., Stasch, Andreas ORCID: https://orcid.org/0000-0002-7407-8287, Kaupp, Martin, Murphy, Damien Martin ORCID: https://orcid.org/0000-0002-5941-4879, Driess, Matthias and Jones, Cameron 2011. A neutral, monomeric germanium(I) radical. Journal of the American Chemical Society 133 (26) , pp. 10074-10077. 10.1021/ja204344e

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Abstract

Stoichiometric reduction of the bulky β-diketiminato germanium(II) chloride complex [(ButNacnac)GeCl] (ButNacnac = [{N(Dip)C(But)}2CH]−, Dip = C6H3Pri2-2,6) with either sodium naphthalenide or the magnesium(I) dimer [{(MesNacnac)Mg}2] (MesNacnac = [(MesNCMe)2CH]−, Mes = mesityl) afforded the radical complex [(ButNacnac)Ge:]• in moderate yields. X-ray crystallographic, EPR/ENDOR spectroscopic, computational, and reactivity studies revealed this to be the first authenticated monomeric, neutral germanium(I) radical.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	American Chemical Society
ISSN:	0002-7863
Last Modified:	03 Dec 2022 11:19
URI:	https://orca.cardiff.ac.uk/id/eprint/12964

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