Rehbein, Julia, Schürmann, M., Preut, H. and Hiersemann, M. 2009. {2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate). Acta Crystallographica Section E - Structure Reports Online E65 (7) , M737. 10.1107/S1600536809020364 |
Abstract
In the title compound, [Cu(C17H30N2O2)(C3H7NO)2][SbF6]2, which is a potential catalyst in the asymmetric Gosteli-Claisen rearrangement, the Cu atom adopts a distorted cis-CuN2O2 square-planar geometry arising from N,N'-bidentate coordination by the chiral ligand and two O-bonded dimethylformamide molecules. Two short C-HO contacts occur within the ligand and two weak intermolecular C-HF bonds may help to establish the packing.
Item Type: | Article |
---|---|
Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
Publisher: | International Union of Crystallography |
ISSN: | 1600-5368 |
Last Modified: | 19 Mar 2016 22:21 |
URI: | https://orca.cardiff.ac.uk/id/eprint/13005 |
Actions (repository staff only)
![]() |
Edit Item |