Biocatalyst mediated regio- and stereo-selective hydroxylation and epoxidation of (Z)-α-santalol

Daramwar, Pankaj P., Srivastava, Prabhakar Lal ORCID: https://orcid.org/0000-0002-8219-6419, Kolet, Swati P. and Thulasiram, Hirekodathakallu V. 2014. Biocatalyst mediated regio- and stereo-selective hydroxylation and epoxidation of (Z)-α-santalol. Organic and Biomolecular Chemistry 12 (7) , pp. 1048-1051. 10.1039/c3ob42174k

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Abstract

Biocatalyst mediated regio- and stereo-selective hydroxylation and epoxidation on (Z)-α-santalol were achieved for the first time, using a fungal strain Mucor piriformis. Four novel metabolites were characterized as 10,11-cis-β-epoxy-α-santalol, 5α-hydroxy-(Z)-α-santalol, 10,11-dihydroxy-α-santalol and 5α-hydroxy-10,11-cis-β-epoxy-α-santalol. Using Amano PS lipase from Burkholderia cepacia, α- and β-isomers of 10,11-cis-epoxy-α-santalol were resolved efficiently.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1477-0520
Date of Acceptance:	23 December 2013
Last Modified:	16 Jan 2024 02:21
URI:	https://orca.cardiff.ac.uk/id/eprint/133382

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