Promoting thermodynamically unfavorable [3,3] rearrangements by chemoselective reduction

Vertesaljai, Peter, Serrano, Roberto, Mannchen, Michael D., Williams, Matthew, Semenova, Evgeniya and Grenning, Alexander J. 2019. Promoting thermodynamically unfavorable [3,3] rearrangements by chemoselective reduction. Organic Letters 21 (14) , pp. 5704-5707. 10.1021/acs.orglett.9b02057 Item availability restricted.

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Abstract

Herein described is a strategy for promoting thermodynamically unfavorable [3,3] Cope rearrangements. 3,3-Dicyano-1,5-dienes that are resistant to the thermal rearrangement can be promoted under reductive conditions. The reduced Cope products are versatile, bifunctional building blocks.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry Cardiff Catalysis Institute (CCI)
Publisher:	American Chemical Society
ISSN:	1523-7060
Date of First Compliant Deposit:	14 September 2020
Date of Acceptance:	2 July 2019
Last Modified:	16 Nov 2024 03:15
URI:	https://orca.cardiff.ac.uk/id/eprint/134832

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