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Promoting thermodynamically unfavorable [3,3] rearrangements by chemoselective reduction

Vertesaljai, Peter, Serrano, Roberto, Mannchen, Michael D., Williams, Matthew, Semenova, Evgeniya and Grenning, Alexander J. 2019. Promoting thermodynamically unfavorable [3,3] rearrangements by chemoselective reduction. Organic Letters 21 (14) , pp. 5704-5707. 10.1021/acs.orglett.9b02057
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Herein described is a strategy for promoting thermodynamically unfavorable [3,3] Cope rearrangements. 3,3-Dicyano-1,5-dienes that are resistant to the thermal rearrangement can be promoted under reductive conditions. The reduced Cope products are versatile, bifunctional building blocks.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Publisher: American Chemical Society
ISSN: 1523-7060
Date of First Compliant Deposit: 14 September 2020
Date of Acceptance: 2 July 2019
Last Modified: 25 Nov 2020 10:12

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