Synthesis and co-ordination chemistry of tris(picolyl-2-carboxyamido-6-pyridyl) methanol: A ligand with a strong preference for trigonal prismatic geometries

Knight, James Christopher, Prabaharan, Ravi, Amoroso, Angelo James ORCID: https://orcid.org/0000-0002-7601-5482, Edwards, Peter Gerald ORCID: https://orcid.org/0000-0001-6999-753X and Ooi, Liling 2011. Synthesis and co-ordination chemistry of tris(picolyl-2-carboxyamido-6-pyridyl) methanol: A ligand with a strong preference for trigonal prismatic geometries. Polyhedron 31 (1) , pp. 457-462. 10.1016/j.poly.2011.09.040

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Abstract

The new tripodal ligand tris(picolyl-2-carboxyamido-6-pyridyl) methanol (L1) has been synthesised via a Pd-catalysed amidocarbonylation reaction in good yield (64%). The ligand has been shown to readily form mononuclear complexes with both Fe(II) and Zn(II). Continuous Shape Mapping calculations have also been performed which confirm the ligands ability to enforce near-perfect trigonal prismatic co-ordination environments upon each of these metal ions.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Elsevier
ISSN:	0277-5387
Last Modified:	18 Oct 2022 13:25
URI:	https://orca.cardiff.ac.uk/id/eprint/13790

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