Knight, James Christopher, Alvarez, Santiago, Amoroso, Angelo James ![]() ![]() |
Official URL: http://dx.doi.org/10.1039/b924651g
Abstract
The synthesis of the novel ligand tris(2,2′-bipyrid-6-yl) methanol (L1) is described. Co-ordination of the ligand to the first row transition metals (Mn2+–Zn2+) as well as Cd2+ showed that the ligand formed complexes close to trigonal prismatic in geometry in the solid state. Analysis of the geometry of the co-ordination spheres showed varying degrees of trigonal prismatic and octahedral character. For each d-electron configuration, this could be related to the relative differences in ligand field stabilisation energies for the two geometries.
Item Type: | Article |
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Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
Publisher: | RSC |
ISSN: | 1477-9226 |
Last Modified: | 18 Oct 2022 13:25 |
URI: | https://orca.cardiff.ac.uk/id/eprint/13801 |
Citation Data
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