Metal-mediated deformylation reactions: synthetic and biological avenues

Patra, Tuhin, Manna, Srimanta and Maiti, Debabrata 2011. Metal-mediated deformylation reactions: synthetic and biological avenues. Angewandte Chemie International Edition 50 (51) , pp. 12140-12142. 10.1002/anie.201103860

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Abstract

No two ways about it: The title reaction is immensely important in synthesis and biology. Whereas biological systems oxygenate aldehydes to generate formate and alkanes or alkenes, synthetic deformylation reactions primarily rely on rapid oxidative addition into the C(O)H bond and subsequent rate‐determining extrusion of CO.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Wiley
ISSN:	1433-7851
Last Modified:	06 May 2023 01:58
URI:	https://orca.cardiff.ac.uk/id/eprint/138416

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