Cardiff University | Prifysgol Caerdydd ORCA
Online Research @ Cardiff 
WelshClear Cookie - decide language by browser settings

Copper mediated decarboxylative direct C-H arylation of heteroarenes with benzoic acids

Patra, Tuhin, Nandi, Sudip, Sahoo, Santosh K. and Maiti, Debabrata 2016. Copper mediated decarboxylative direct C-H arylation of heteroarenes with benzoic acids. Chemical Communications 52 (7) , pp. 1432-1435. 10.1039/C5CC08367B

[thumbnail of c5cc08367b.pdf] PDF - Published Version
Available under License Creative Commons Attribution Non-commercial.

Download (2MB)

Abstract

Decarboxylative coupling reactions to date require a stoichiometric oxidant (such as copper and silver salts) for decarboxylation purposes along with a metal catalyst (e.g. palladium) for cross-coupling. In this communication, an economic and sustainable approach by using a simple copper salt was developed in the presence of molecular oxygen as the sole oxidant. A wide range of 5-membered heteroarenes undergo aryl–heteroaryl cross-coupling with electron deficient aryl carboxylic acids.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Date of First Compliant Deposit: 18 February 2021
Date of Acceptance: 17 November 2015
Last Modified: 18 Feb 2021 14:30
URI: https://orca.cardiff.ac.uk/id/eprint/138426

Citation Data

Cited 67 times in Scopus. View in Scopus. Powered By Scopus® Data

Actions (repository staff only)

Edit Item Edit Item

Downloads

Downloads per month over past year

View more statistics