Patra, Tuhin, Bag, Sukdev, Kancherla, Rajesh, Mondal, Anirban, Dey, Aniruddha, Pimparkar, Sandeep, Agasti, Soumitra, Modak, Atanu and Maiti, Debabrata 2016. Palladium‐catalyzed directed para C−H functionalization of phenols. Angewandte Chemie International Edition 55 (27) , pp. 7751-7755. 10.1002/anie.201601999 |
Official URL: http://dx.doi.org/10.1002/anie.201601999
Abstract
Various practical methods for the selective C−H functionalization of the ortho and recently also of the meta position of an arene have already been developed. Following our recent development of the directing‐group‐assisted para C−H functionalization of toluene derivatives, we herein report the first remote para C−H functionalization of phenol derivatives by using a recyclable silicon‐containing biphenyl‐based template. The effectiveness of this strategy was illustrated with different synthetic elaborations and by the synthesis of various phenol‐based natural products.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Publisher: | Wiley |
ISSN: | 1433-7851 |
Last Modified: | 06 May 2023 01:58 |
URI: | https://orca.cardiff.ac.uk/id/eprint/138428 |
Citation Data
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