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Palladium‐catalyzed directed para C−H functionalization of phenols

Patra, Tuhin, Bag, Sukdev, Kancherla, Rajesh, Mondal, Anirban, Dey, Aniruddha, Pimparkar, Sandeep, Agasti, Soumitra, Modak, Atanu and Maiti, Debabrata 2016. Palladium‐catalyzed directed para C−H functionalization of phenols. Angewandte Chemie International Edition 55 (27) , pp. 7751-7755. 10.1002/anie.201601999

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Various practical methods for the selective C−H functionalization of the ortho and recently also of the meta position of an arene have already been developed. Following our recent development of the directing‐group‐assisted para C−H functionalization of toluene derivatives, we herein report the first remote para C−H functionalization of phenol derivatives by using a recyclable silicon‐containing biphenyl‐based template. The effectiveness of this strategy was illustrated with different synthetic elaborations and by the synthesis of various phenol‐based natural products.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Wiley
ISSN: 1433-7851
Last Modified: 06 May 2023 01:58

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