Enhancing the rigidity of a network polymer of intrinsic microporosity by the combined use of phthalocyanine and triptycene components

Hashem, Mohammed ORCID: https://orcid.org/0000-0002-2582-8440, Bezzu, Caterina Grazia, Kariuki, Benson ORCID: https://orcid.org/0000-0002-8658-3897 and McKeown, Neil B. 2011. Enhancing the rigidity of a network polymer of intrinsic microporosity by the combined use of phthalocyanine and triptycene components. Polymer Chemistry 2 (10) , pp. 2190-2192. 10.1039/c1py00288k

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Abstract

By combining both triptycene and multifunctional phthalocyanine components within a polymer of intrinsic microporosity (PIM), a polymer network of apparent BET surface of 806 m2 g−1 was obtained that appears to possess a highly rigid structure as determined from the shape of its nitrogen adsorption isotherm, which is similar in appearance to that of a crystalline microporous material such as a zeolite.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1759-9954
Funders:	EPSRC
Last Modified:	18 Oct 2022 13:27
URI:	https://orca.cardiff.ac.uk/id/eprint/13933

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