On the spontaneous induction of chirality in the preparation of Werner's complex cis-[CoBr(NH3)(en)2]Br2

Guo, Fang ORCID: https://orcid.org/0000-0001-5014-2830, Casadesus, Meritxell, Cheung, Eugene, Coogan, Michael Peter and Harris, Kenneth David Maclean ORCID: https://orcid.org/0000-0001-7855-8598 2006. On the spontaneous induction of chirality in the preparation of Werner's complex cis-[CoBr(NH3)(en)2]Br2. Chemical Communications (17) , pp. 1854-1856. 10.1039/b601530a

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Abstract

The product obtained directly from the standard reaction to produce Werner’s complex cis-[CoBr(NH3)(en)2]Br2 is shown, via structure determination from powder X-ray diffraction data, to be a racemic crystalline phase; implications of this observation in relation to previous reports that this reaction leads to significant enantiomeric excesses are discussed.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	RSC Publishing
ISSN:	1359-7345
Last Modified:	17 Oct 2022 08:53
URI:	https://orca.cardiff.ac.uk/id/eprint/1397

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