Development of a system for clean and regioselective mononitration of aromatic compounds involving a microporous solid, dinitrogen tetroxide and air

Smith, Keith, Almeer, Saeed, Black, Steven J. and Peters, Christelle 2002. Development of a system for clean and regioselective mononitration of aromatic compounds involving a microporous solid, dinitrogen tetroxide and air. Journal of Materials Chemistry 12 (11) , pp. 3285-3289. 10.1039/b204088c

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Abstract

Nitration of aromatic compounds using a zeolite as a solid inorganic catalyst and a combination of dinitrogen tetroxide and oxygen or air as the nitrating reagent, in open or sealed systems, leads to high yields and significant para selectivities for halogenobenzenes and other aromatics in a relatively clean process. The material used as catalyst has a strong influence on the reaction.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Additional Information:	Basis of a presentation given at Materials Discussion No. 5, 22-25 September 2002, Madrid, Spain
Publisher:	Royal Society of Chemistry
ISSN:	0959-9428
Last Modified:	05 May 2023 13:14
URI:	https://orca.cardiff.ac.uk/id/eprint/14261

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