| Smith, Keith and Roberts, Simon D. 2000. Regioselective dialkylation of naphthalene. Catalysis Today 60 (3-4) , pp. 227-233. 10.1016/S0920-5861(00)00339-4 | 
      Official URL: http://www.sciencedirect.com/science/article/pii/S...
    
  
  
    Abstract
The alkylation of naphthalene using tert-butanol in cyclohexane over a dealuminated H-Mordenite (HM) zeolite has been optimised to give a 60% yield of 2,6-di-tert-butylnaphthalene with a 2,6/2,7 ratio of over 50. This has been achieved by varying the reaction time, temperature, pressure, solvent, amount of tert-butanol, solvent and catalyst, Si/Al ratio of the catalyst, and the mode of addition.
| Item Type: | Article | 
|---|---|
| Status: | Published | 
| Schools: | Schools > Chemistry | 
| Subjects: | Q Science > QD Chemistry | 
| Uncontrolled Keywords: | Alkylation; Naphthalene; H-Mordenite; Regioselectivity | 
| Publisher: | Elsevier | 
| ISSN: | 0920-5861 | 
| Last Modified: | 04 Jun 2017 02:57 | 
| URI: | https://orca.cardiff.ac.uk/id/eprint/14293 | 
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