Smith, Keith and Roberts, Simon D. 2000. Regioselective dialkylation of naphthalene. Catalysis Today 60 (3-4) , pp. 227-233. 10.1016/S0920-5861(00)00339-4 |
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Abstract
The alkylation of naphthalene using tert-butanol in cyclohexane over a dealuminated H-Mordenite (HM) zeolite has been optimised to give a 60% yield of 2,6-di-tert-butylnaphthalene with a 2,6/2,7 ratio of over 50. This has been achieved by varying the reaction time, temperature, pressure, solvent, amount of tert-butanol, solvent and catalyst, Si/Al ratio of the catalyst, and the mode of addition.
Item Type: | Article |
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Status: | Published |
Schools: | Schools > Chemistry |
Subjects: | Q Science > QD Chemistry |
Uncontrolled Keywords: | Alkylation; Naphthalene; H-Mordenite; Regioselectivity |
Publisher: | Elsevier |
ISSN: | 0920-5861 |
Last Modified: | 04 Jun 2017 02:57 |
URI: | https://orca.cardiff.ac.uk/id/eprint/14293 |
Citation Data
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