Cavill, Julie L., Elliott, Richard L., Evans, Gareth James S., Jones, Ian L., Platts, James Alexis  ORCID: https://orcid.org/0000-0002-1008-6595, Ruda, Antonio M. and Tomkinson, Nicholas Charles Oliver
2006.
The α-effect in iminium ion catalysis.
Tetrahedron
62
(2-3)
, pp. 410-421.
10.1016/j.tet.2005.08.110
|
Abstract
The ?-effect can be used as an effective means to promote iminium ion catalysed transformations, providing acyclic scaffolds to aid in catalyst design. A thorough investigation of the structure–activity relationship of the catalyst architecture reveals optimal substituents of a disubstituted carbamate and a secondary alkyl group around a hydrazine scaffold. Molecular modelling investigations provide a mechanistic rationale to the results observed.
| Item Type: | Article |
|---|---|
| Date Type: | Publication |
| Status: | Published |
| Schools: | Schools > Chemistry |
| Uncontrolled Keywords: | ?-Effect; Iminium ion catalysis; DFT calculations |
| ISSN: | 00404020 |
| Last Modified: | 17 Oct 2022 08:54 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/1430 |
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