Frustrated Lewis pairs in organic synthesis

Heard, Matthew J., Stefkova, Katarina, van Ingen, Yara and Melen, Rebecca L. ORCID: https://orcid.org/0000-0003-3142-2831 2022. Frustrated Lewis pairs in organic synthesis. Parkin, Gerard, Meyer, Karsten and O'Hare, Dermot, eds. Comprehensive Organometallic Chemistry IV, Vol. 11. Elsevier, pp. 563-605. (10.1016/B978-0-12-820206-7.00041-X)

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Abstract

In 2006, Stephan defined frustrated Lewis pairs and, over the last 15 years, these systems have developed from chemical novelties to increasingly commonplace catalysts, with many research groups developing their capabilities to surpass those of transition metal catalysts. This book article aims to discuss the catalytic uses of frustrated Lewis pairs focusing on their application within organic synthesis, with a discussion on hydrogenation catalysis, air and moisture stable FLPs, enantioselective FLPs, 1,2-hydrofunctionalization catalysis, cyclization catalysis, and a brief look at the recent use of FLPs within radical chemistry.

Item Type:	Book Section
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry Research Institutes & Centres > Cardiff Catalysis Institute (CCI)
Publisher:	Elsevier
ISBN:	9780128202067
Last Modified:	23 Jun 2025 10:00
URI:	https://orca.cardiff.ac.uk/id/eprint/143253

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