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Distribution of active site types on Au nanoparticles with different structures: study of thermal dependence

Svalova, A.I. and Stishenko, P.V. 2016. Distribution of active site types on Au nanoparticles with different structures: study of thermal dependence. Procedia Engineering 152 , pp. 67-72. 10.1016/j.proeng.2016.07.629

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Abstract

For gold nanoparticles dependencies of low-coordinated atoms count and areas of different faces from nanoparticle size, shape and structure and temperature have been studied. The following recommendations for catalyst developers are proposed: for catalysis of reactions that occur on (111) face icosahedral nanoparticles smaller than 400 atoms must be preferred; reaction that occur on (100) and (110) faces and near low-coordinated atoms, should be better catalyzed by FCC nanoparticles; it should be taken into account, that temperature growth decreases amount of atoms on (111) and (110) faces, and, increases number of low-coordinated atoms and an area of (100) faces.

Item Type: Article
Date Type: Published Online
Status: Published
Schools: Chemistry
Publisher: Elsevier
ISSN: 1877-7058
Date of First Compliant Deposit: 4 October 2021
Last Modified: 04 Oct 2021 13:30
URI: https://orca.cardiff.ac.uk/id/eprint/143473

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