Jerwood, Kimberley, Lowy, Phoebe, Deeming, Laura, Kariuki, Benson M. ![]() ![]() ![]() |
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Official URL: http://dx.doi.org/10.1039/D1DT02928B
Abstract
Highly diastereoselective coordination of unsymmetrical cationic 2,2′-bipyridine ligands bearing a chiral amidinium substituent to [Re(CO)3Cl] and [Ir(PhPy)2]+ cores is reported. Binding strength and stereoselectivity have been correlated with the position of the amidinium group on the bipy. The 4-, 5- and 6-substituted ligands all produce C-[Re(CO)3(LH)Cl]X selectively, while only the 4-derivative gives preferred formation of Δ-[Ir(Phpy)2(4-LH)](BF4)2.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Additional Information: | This article is licensed under a Creative Commons Attribution 3.0 Unported Licence |
Publisher: | Royal Society of Chemistry |
ISSN: | 1477-9226 |
Date of First Compliant Deposit: | 27 October 2021 |
Date of Acceptance: | 8 October 2021 |
Last Modified: | 19 May 2023 17:35 |
URI: | https://orca.cardiff.ac.uk/id/eprint/145108 |
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