C3 Chirality in Polymerization Catalysis: A Highly Active Dicationic Scandium(III) Catalyst for the Isoselective Polymerization of 1-Hexene

Ward, Benjamin David ORCID: https://orcid.org/0000-0003-1406-5940, Bellemin-Laponnaz, Stephane and Gade, Lutz H. 2005. C3 Chirality in Polymerization Catalysis: A Highly Active Dicationic Scandium(III) Catalyst for the Isoselective Polymerization of 1-Hexene. Angewandte Chemie International Edition 44 (11) , pp. 1668-1671. 10.1002/anie.200462804

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Abstract

A tactical approach: C3-chiral ancillary ligands such as tris(oxazolinyl)ethane allow stereocontrol in olefin polymerization (see scheme). An alkyl ScIII catalyst polymerizes 1-hexene with activities ranging from 2000 to 36 000 kg mol−1 h−1 (at −30 to +21 °C) and good tacticity control at low temperatures.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	homogeneous catalysis;polymerization;polymers;scandium;stereocontrol
ISSN:	15213773
Last Modified:	17 Oct 2022 08:55
URI:	https://orca.cardiff.ac.uk/id/eprint/1513

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