Ward, Benjamin David ![]() |
Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...
Abstract
A tactical approach: C3-chiral ancillary ligands such as tris(oxazolinyl)ethane allow stereocontrol in olefin polymerization (see scheme). An alkyl ScIII catalyst polymerizes 1-hexene with activities ranging from 2000 to 36 000 kg mol−1 h−1 (at −30 to +21 °C) and good tacticity control at low temperatures.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QD Chemistry |
Uncontrolled Keywords: | homogeneous catalysis;polymerization;polymers;scandium;stereocontrol |
ISSN: | 15213773 |
Last Modified: | 17 Oct 2022 08:55 |
URI: | https://orca.cardiff.ac.uk/id/eprint/1513 |
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