Selective mono-chlorination of aromatic compounds under mild conditions by tert-butyl hypochlorite in the presence of zeolites

Smith, Keith, Butters, Michael, Paget, Walter E., Goubet, Dominique, Fromentin, Emmanuelle and Nay, Barry 1999. Selective mono-chlorination of aromatic compounds under mild conditions by tert-butyl hypochlorite in the presence of zeolites. Green Chemistry 1 (2) , pp. 83-90. 10.1039/A901395D

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Abstract

tert-Butyl hypochlorite/HNa faujasite X in acetonitrile represents an efficient and highly regioselective system for mono-chlorination of a wide range of mono- and di-substituted aromatic substrates in mild conditions. Partially protonated faujasite X is far superior to amorphous silicas and to other zeolites in terms of efficiency and regioselectivity. Advantages of t e r t- b u t y l hypochlorite over other chlorinating reagents have been demonstrated. The method is suitable for large scale work.

Item Type:	Article
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1463-9262
Last Modified:	04 Jun 2017 03:00
URI:	https://orca.cardiff.ac.uk/id/eprint/15194

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