Total synthesis of (+)-crocacin D

Dias, Luiz C., Gonzaga De Oliveira, Luciana, Vilcachagua, Janaína D. and Nigsch, Florian 2005. Total synthesis of (+)-crocacin D. The Journal of Organic Chemistry 70 (6) , pp. 2225-2234. 10.1021/jo047732k

Full text not available from this repository.

Abstract

The total synthesis of (+)-crocacin D is described. The convergent asymmetric synthesis relies on the use of a Stille cross-coupling between an (E)-vinyl stannane with an (E)-vinyl iodide to establish the (E,E)-dienamide moiety followed by a mild and efficient copper-catalyzed coupling between (+)-crocacin C and a (Z)-vinyl iodide to establish the challenging (Z)-enamide function.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	American Chemical Society
ISSN:	0022-3263
Last Modified:	14 Nov 2022 16:05
URI:	https://orca.cardiff.ac.uk/id/eprint/153689

Citation Data

Cited 64 times in Scopus. View in Scopus. Powered By Scopus® Data

Actions (repository staff only)

Edit Item