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Total synthesis of (+)-crocacin D

Dias, Luiz C., Gonzaga De Oliveira, Luciana, Vilcachagua, Janaína D. and Nigsch, Florian 2005. Total synthesis of (+)-crocacin D. The Journal of Organic Chemistry 70 (6) , pp. 2225-2234. 10.1021/jo047732k

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The total synthesis of (+)-crocacin D is described. The convergent asymmetric synthesis relies on the use of a Stille cross-coupling between an (E)-vinyl stannane with an (E)-vinyl iodide to establish the (E,E)-dienamide moiety followed by a mild and efficient copper-catalyzed coupling between (+)-crocacin C and a (Z)-vinyl iodide to establish the challenging (Z)-enamide function.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: American Chemical Society
ISSN: 0022-3263
Last Modified: 14 Nov 2022 16:05

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