Chen, Lu S., Mantovani, Simone M., Gonzaga De Oliveira, Luciana, Duarte, Marta C.T. and Marsaioli, Anita J. 2008. 1,2-Octanediol deracemization by stereoinversion using whole cells. Journal of Molecular Catalysis B: Enzymatic 54 (1-2) , pp. 50-54. 10.1016/j.molcatb.2007.11.022 |
Official URL: http://dx.doi.org/10.1016/j.molcatb.2007.11.022
Abstract
This paper describes the stereoinversion of (R)-1,2-octanediol promoted by Aspergillus niger CCT 1435 and Candida albicans CCT 0776 from Brazilian collections. Racemic 1,2-octanediol can be converted into (S)-1,2-octanediol with 70% isolated yield and 99% ee in 10 h using C. albicans. This is one of the best results in the literature and on-going experiments indicate that the reaction rate can be further accelerated.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Publisher: | Elsevier |
ISSN: | 1381-1177 |
Date of Acceptance: | 29 November 2007 |
Last Modified: | 14 Nov 2022 16:05 |
URI: | https://orca.cardiff.ac.uk/id/eprint/153694 |
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