One-pot synthesis of styrene derivatives from allyl silanes via b(c6f5)3-catalyzed isomerization-Hiyama coupling

Kustiana, Betty A., Melen, Rebecca L. ORCID: https://orcid.org/0000-0003-3142-2831 and Morrill, Louis C. ORCID: https://orcid.org/0000-0002-6453-7531 2022. One-pot synthesis of styrene derivatives from allyl silanes via b(c6f5)3-catalyzed isomerization-Hiyama coupling. Organic Letters 24 (47) , pp. 8694-8697. 10.1021/acs.orglett.2c03584

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Abstract

Herein, we report a one-pot synthesis of styrene derivatives via a novel B(C6F5)3-catalyzed E-selective isomerization of readily accessible allyl silanes and subsequent Hiyama coupling of the versatile alkenyl silane intermediates. This one-pot, two-step approach enables access to a broad range of styrene derivatives, including those containing Lewis basic functional groups, that cannot be accessed via the previously developed B(C6F5)3-catalyzed isomerization of allyl benzenes.

Item Type:	Article
Date Type:	Published Online
Status:	Published
Schools:	Schools > Chemistry Research Institutes & Centres > Cardiff Catalysis Institute (CCI)
Publisher:	American Chemical Society
ISSN:	1523-7060
Funders:	School of Chemistry, Cardiff University and the Schlumberger Foundation for a Faculty of the Future Fellowship (B.A.K.).
Date of First Compliant Deposit:	2 December 2022
Date of Acceptance:	11 November 2022
Last Modified:	29 Aug 2024 12:49
URI:	https://orca.cardiff.ac.uk/id/eprint/154628

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