Platinum(IV) centres with agostic interactions from either sp(2) or sp(3) C-H bonds

Crosby, Sarah H., Deeth, Robert J., Clarkson, Guy J. and Rourke, Jonathan P. ORCID: https://orcid.org/0000-0002-8961-1021 2011. Platinum(IV) centres with agostic interactions from either sp(2) or sp(3) C-H bonds. Dalton Transactions 40 (6) , pp. 1227-1229. 10.1039/c0dt01428a

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Abstract

Agostic complexes of platinum(IV) have been isolated and characterised. A Pt(II) sp3 agostic complex maintains the agostic interaction upon oxidation giving a Pt(IV) sp3 agostic complex; in another Pt(IV) complex the agostic interaction from an sp2 C–H bond is sufficient to displace another ligand.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1477-9226
Date of Acceptance:	2 December 2010
Last Modified:	03 Apr 2023 15:45
URI:	https://orca.cardiff.ac.uk/id/eprint/155166

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