Substituent effects on the cyclo-manganation reaction - X-ray crystal structure of Mn{2-(Bu-n-N=CH)5-(NO2)C6H3}(CO)(4)

Morton, C., Duncalf, D.J. and Rourke, J.P. ORCID: https://orcid.org/0000-0002-8961-1021 1997. Substituent effects on the cyclo-manganation reaction - X-ray crystal structure of Mn{2-(Bu-n-N=CH)5-(NO2)C6H3}(CO)(4). Journal of Organometallic Chemistry 530 (1-2) , pp. 19-25. 10.1016/S0022-328X(96)06663-6

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Abstract

The cyclometallation reaction between methylmanganese pentacarbonyl and a number of Schiff's bases has been studied. The dependence of the rate of reaction upon ligand substituents has been investigated, demonstrating a rate enhancement with more electron-rich ligands. The X-ray structure of Mn2-(nBu-N=CH)5-(NO2)C6H3(CO)4 has been determined.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
Publisher:	Elsevier
ISSN:	0022-328X
Last Modified:	03 Apr 2023 16:00
URI:	https://orca.cardiff.ac.uk/id/eprint/155186

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