Morton, C., Duncalf, D.J. and Rourke, J.P.  ORCID: https://orcid.org/0000-0002-8961-1021
1997.
Substituent effects on the cyclo-manganation reaction - X-ray crystal structure of Mn{2-(Bu-n-N=CH)5-(NO2)C6H3}(CO)(4).
Journal of Organometallic Chemistry
530
(1-2)
, pp. 19-25.
10.1016/S0022-328X(96)06663-6
|
Official URL: https://dx.doi.org/10.1016/S0022-328X(96)06663-6
Abstract
The cyclometallation reaction between methylmanganese pentacarbonyl and a number of Schiff's bases has been studied. The dependence of the rate of reaction upon ligand substituents has been investigated, demonstrating a rate enhancement with more electron-rich ligands. The X-ray structure of Mn2-(nBu-N=CH)5-(NO2)C6H3(CO)4 has been determined.
| Item Type: | Article |
|---|---|
| Date Type: | Publication |
| Status: | Published |
| Schools: | Schools > Chemistry |
| Publisher: | Elsevier |
| ISSN: | 0022-328X |
| Last Modified: | 03 Apr 2023 16:00 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/155186 |
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