Carbene or zwitterion? Competition in organoplatinum complexes

Newman, C.P., Clarkson, G.J., Alcock, N.W. and Rourke, J.P. ORCID: https://orcid.org/0000-0002-8961-1021 2006. Carbene or zwitterion? Competition in organoplatinum complexes. Dalton Transactions (27) , pp. 3321-3325. 10.1039/b517874f

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Abstract

The reaction of a known dimeric dicarbene complex of platinum with a number of ligands results in four new platinum complexes. The structure of the new complexes is described: one complex must exist as a neutral complex with no charge separation, and the other three are assigned a charge-separated (zwitterionic) structure, rather than a carbene form, on the basis of comparative 13C NMR shifts.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1477-9234
Last Modified:	28 Apr 2023 13:30
URI:	https://orca.cardiff.ac.uk/id/eprint/155189

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