Newman, C.P., Clarkson, G.J., Alcock, N.W. and Rourke, J.P.  ORCID: https://orcid.org/0000-0002-8961-1021
2006.
Carbene or zwitterion? Competition in organoplatinum complexes.
Dalton Transactions
(27)
, pp. 3321-3325.
10.1039/b517874f
|
Official URL: https://dx.doi.org/10.1039/b517874f
Abstract
The reaction of a known dimeric dicarbene complex of platinum with a number of ligands results in four new platinum complexes. The structure of the new complexes is described: one complex must exist as a neutral complex with no charge separation, and the other three are assigned a charge-separated (zwitterionic) structure, rather than a carbene form, on the basis of comparative 13C NMR shifts.
| Item Type: | Article |
|---|---|
| Date Type: | Publication |
| Status: | Published |
| Schools: | Schools > Chemistry |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1477-9234 |
| Last Modified: | 28 Apr 2023 13:30 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/155189 |
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