Heterobimetallic rollover derivatives

Petretto, Giacomo L., Rourke, Jonathan P. ORCID: https://orcid.org/0000-0002-8961-1021, Maidich, Luca, Stoccoro, Sergio, Cinellu, Maria Agostina, Minghetti, Giovanni, Clarkson, Guy J. and Zucca, Antonio 2012. Heterobimetallic rollover derivatives. Organometallics 31 (8) , pp. 2971-2977. 10.1021/om200660a

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Abstract

Heterobimetallic complexes with metal centers connected by a small delocalized ligand constitute an interesting class of compounds. Here we report that starting from the mononuclear platinum(II) rollover complexes [Pt(bipy-H)(L)Cl] (bipy-H = 2,2′-bipyridine C(3′)-N cyclometalated, L= DMSO, PPh3) a second rollover cyclometalation may produce a series of Pt(II)/Pd(II) heterobimetallic complexes where the two metals are linked by the planar, highly delocalized, doubly deprotonated 2,2′-bipyridine.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	American Chemical Society
ISSN:	0276-7333
Last Modified:	03 Apr 2023 15:30
URI:	https://orca.cardiff.ac.uk/id/eprint/155196

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