Anion inclusion by a calix[4]arene complex: a contrast between tetranuclear gold(I) and copper(I) complexes

Xu, W., Rourke, J.P. ORCID: https://orcid.org/0000-0002-8961-1021, Vittal, J.J. and Puddephatt, R.J. 1993. Anion inclusion by a calix[4]arene complex: a contrast between tetranuclear gold(I) and copper(I) complexes. Journal of the chemical society-chemical communications (2) , pp. 145-147. 10.1039/c39930000145

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Abstract

A tetradentate ligand, L, derived from a bowl-shaped calix[4]resorcinarene by incorporation of four phosphonite donors, has been used in the synthesis of several tetragold(I) and tetracopper(I) complexes, such as [L(AuCl)4] and [pyH]+[LCu4(µ-Cl)4(µ3-Cl)]–; the halide inclusion found for the copper complexes is unique in calixarene chemistry.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Schools > Chemistry
ISSN:	00224936
Last Modified:	28 Apr 2023 13:30
URI:	https://orca.cardiff.ac.uk/id/eprint/155227

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