Alotaibi, Nusaybah, Babaahmadi, Rasool, Pramanik, Milan, Kaehler, Tanja, Dasgupta, Ayan, Richards, Emma  ORCID: https://orcid.org/0000-0001-6691-2377, Ariafard, Alireza, Wirth, Thomas ORCID: https://orcid.org/0000-0002-8990-0667 and Melen, Rebecca L. ORCID: https://orcid.org/0000-0003-3142-2831
2023.
B(3,4,5-F3H2C6)3 Lewis acid-catalysed C3-allylation of indoles.
Dalton Transactions
52
(16)
10.1039/d3dt00745f
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License URL: http://creativecommons.org/licenses/by/3.0/
License Start date: 11 April 2023
Official URL: https://doi.org/10.1039/d3dt00745f
Abstract
Herein we report the B(3,4,5-F3H2C6)3-catalysed C3-allylation of indoles using allylic esters. 25 examples of C3-allylated products are presented in up to 97% yield. The mechanism for the reaction was explored using detailed Density Functional Theory (DFT) studies.
| Item Type: | Article |
|---|---|
| Date Type: | Publication |
| Status: | Published |
| Schools: | Schools > Chemistry |
| Additional Information: | License information from Publisher: LICENSE 1: URL: http://creativecommons.org/licenses/by/3.0/, Start Date: 2023-04-11 |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1477-9226 |
| Funders: | EPSRC |
| Date of First Compliant Deposit: | 18 April 2023 |
| Date of Acceptance: | 10 April 2023 |
| Last Modified: | 05 Jan 2024 06:57 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/158921 |
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