Isolated PdO sites on SiO2-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation

Ziarko, Aleksandra, Slater, Thomas J. A. ORCID: https://orcid.org/0000-0003-0372-1551, Isaacs, Mark A., Durndell, Lee J. and Parlett, Christopher M. A. 2023. Isolated PdO sites on SiO2-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation. Catalysis Science & Technology 13 (12) , pp. 3483-3488. 10.1039/d3cy00198a

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Abstract

Catalytic allylic alcohol oxidation to aldehydes is an industrial process that necessitates chemoselectivity. Surface PdO (on Pd) enables this transformation but does not represent optimal metal utilisation. Here we report a facile synthesis route to produce isolated surface PdO catalytic sites on an earth-abundant metal (NiO) for cinnamyl alcohol oxidation.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Cardiff Catalysis Institute (CCI) Chemistry
Additional Information:	License information from Publisher: LICENSE 1: URL: http://creativecommons.org/licenses/by/3.0/, Start Date: 2023-05-12
Publisher:	Royal Society of Chemistry
ISSN:	2044-4753
Date of First Compliant Deposit:	23 May 2023
Date of Acceptance:	11 May 2023
Last Modified:	29 Jun 2023 18:01
URI:	https://orca.cardiff.ac.uk/id/eprint/159895

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