Murtaza, Ayesha, Ulhaq, Zia, Shirinfar, Bahareh, Rani, Sadia, Aslam, Samina, Martins, Guilherme M. and Ahmed, Nisar  ORCID: https://orcid.org/0000-0002-7954-5251
2023.
Arenes and heteroarenes C-H functionalization under enabling conditions: electrochemistry, photoelectrochemistry & flow technology.
Chemical Record
23
(10)
, e202300119.
10.1002/tcr.202300119
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Abstract
C−H bond functionalization generates molecular complexity in single-step transformation. However, the activation of C−H bonds requires expensive metals or stoichiometric amounts of oxidizing/reducing species. In many cases, they often require pre-functionalization of starting molecules. Such pre-activating measures cause waste generation and their separation from the final product is also troublesome. In such a scenario, reactions activating elements generating from renewable energy resources such as electricity and light would be more efficient, green, and cost-effective. Further, incorporation of growing flow technology in chemical transformation processes will accelerate the safer accesses of valuable products. Arenes & heteroarenes are ubiquitous in pharmaceuticals, natural products, medicinal compounds, and other biologically important molecules. Herein, we discussed enabling tools and technologies used for the recent C−H bonds functionalization of arenes and heteroarenes.
| Item Type: | Article |
|---|---|
| Date Type: | Publication |
| Status: | Published |
| Schools: | Schools > Chemistry |
| Publisher: | Chemical Society of Japan |
| ISSN: | 1527-8999 |
| Date of First Compliant Deposit: | 31 May 2023 |
| Date of Acceptance: | 18 May 2023 |
| Last Modified: | 24 Oct 2023 12:49 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/160084 |
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