Arenes and heteroarenes C-H functionalization under enabling conditions: electrochemistry, photoelectrochemistry & flow technology

Murtaza, Ayesha, Ulhaq, Zia, Shirinfar, Bahareh, Rani, Sadia, Aslam, Samina, Martins, Guilherme M. and Ahmed, Nisar ORCID: https://orcid.org/0000-0002-7954-5251 2023. Arenes and heteroarenes C-H functionalization under enabling conditions: electrochemistry, photoelectrochemistry & flow technology. Chemical Record 23 (10) , e202300119. 10.1002/tcr.202300119

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Abstract

C−H bond functionalization generates molecular complexity in single-step transformation. However, the activation of C−H bonds requires expensive metals or stoichiometric amounts of oxidizing/reducing species. In many cases, they often require pre-functionalization of starting molecules. Such pre-activating measures cause waste generation and their separation from the final product is also troublesome. In such a scenario, reactions activating elements generating from renewable energy resources such as electricity and light would be more efficient, green, and cost-effective. Further, incorporation of growing flow technology in chemical transformation processes will accelerate the safer accesses of valuable products. Arenes & heteroarenes are ubiquitous in pharmaceuticals, natural products, medicinal compounds, and other biologically important molecules. Herein, we discussed enabling tools and technologies used for the recent C−H bonds functionalization of arenes and heteroarenes.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	Chemical Society of Japan
ISSN:	1527-8999
Date of First Compliant Deposit:	31 May 2023
Date of Acceptance:	18 May 2023
Last Modified:	24 Oct 2023 12:49
URI:	https://orca.cardiff.ac.uk/id/eprint/160084

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