Frustrated radical pairs in selective functionalization of inert aliphatic C-H bonds

Pramanik, Milan and Melen, Rebecca L. ORCID: https://orcid.org/0000-0003-3142-2831 2023. Frustrated radical pairs in selective functionalization of inert aliphatic C-H bonds. Chem 9 (8) , pp. 2060-2062. 10.1016/j.chempr.2023.07.012

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Abstract

In this preview, we highlight Lin and co-workers’ recent findings published in Nature on the non-directed functionalization of chemically inert aliphatic C‒H bonds through the use of the hexamethyldisilazide anion (HMDS–, a reductant) and N-oxoammonium cation (TEMPO+, an oxidant) as a new class of frustrated radical pair.

Item Type:	Article
Date Type:	Published Online
Status:	Published
Schools:	Chemistry Cardiff Catalysis Institute (CCI)
Publisher:	Cell Press
ISSN:	2451-9294
Funders:	EPSRC
Date of First Compliant Deposit:	10 October 2023
Date of Acceptance:	10 August 2023
Last Modified:	10 Aug 2024 01:30
URI:	https://orca.cardiff.ac.uk/id/eprint/163104

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