Pramanik, Milan and Melen, Rebecca L.  ORCID: https://orcid.org/0000-0003-3142-2831
2023.
Frustrated radical pairs in selective functionalization of inert aliphatic C-H bonds.
Chem
9
(8)
, pp. 2060-2062.
10.1016/j.chempr.2023.07.012
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Official URL: http://dx.doi.org/10.1016/j.chempr.2023.07.012
Abstract
In this preview, we highlight Lin and co-workers’ recent findings published in Nature on the non-directed functionalization of chemically inert aliphatic C‒H bonds through the use of the hexamethyldisilazide anion (HMDS–, a reductant) and N-oxoammonium cation (TEMPO+, an oxidant) as a new class of frustrated radical pair.
| Item Type: | Article |
|---|---|
| Date Type: | Published Online |
| Status: | Published |
| Schools: | Schools > Chemistry Research Institutes & Centres > Cardiff Catalysis Institute (CCI) |
| Publisher: | Cell Press |
| ISSN: | 2451-9294 |
| Funders: | EPSRC |
| Date of First Compliant Deposit: | 10 October 2023 |
| Date of Acceptance: | 10 August 2023 |
| Last Modified: | 10 Aug 2024 01:30 |
| URI: | https://orca.cardiff.ac.uk/id/eprint/163104 |
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